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Have you ever wondered how you could be more productive? How could you organize your timetable or school notes effectively? Perhaps you had some money and needed to make a budget to allocate it properly? Well, I'm willing to bet you ended up using either list if all tasks at hand are different or an Excel table if you would like…
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Jetzt kostenlos anmeldenHave you ever wondered how you could be more productive? How could you organize your timetable or school notes effectively? Perhaps you had some money and needed to make a budget to allocate it properly?
Well, I'm willing to bet you ended up using either list if all tasks at hand are different or an Excel table if you would like to group some of them together neatly. Now you see back in the day, and we are talking really back like 1800s there was no excel and people still managed to survive, which is quite frankly mind-boggling to me.
But they still made tables to organize their time, finances, and some people like Mendeleev used tables to organize all kinds of different things. What did he choose to organize? Well, everything that builds up the world, all elements in one table! Quite the undertaking right? Let's see what he came up with and how did that hold up against the test of time!
The periodic table of elements is an essential tool in the study of chemistry, and every high school student has encountered it at some point. However, where did the periodic table come from exactly? By the way , why is it called periodic anyway?
Starting from the Nineteenth century, scientists used a lot of parameters and criteria to identify and group elements. For example, German scientist Johann Wolfgang Döbereiner observed that Calcium, Barium, and Strontium have similar qualities thus named this set of three elements a triad. In 1863, British chemist John Newlands classified the known elements into seven groups of eight elements each and defined the law of octaves.
According to the law of octaves, every eighth element organized in descending order of its atomic masses will have similar properties.
Today this law is known to be false, however, this is still an important piece of chemistry history.
I am sure you know by now that, with anything in science, there is a lot of trial and error. The periodic table went through a similar process as well. Different scientists tried to put together a periodic table that represented all elements (both in nature and man-made). However, the man credited with contributing the most to the periodic table was Russian scientist Dimitri Mendeleev.
In 1869 Mendeleev proposed that the properties of the elements were a function of their atomic mass. The Russian scientist, alongside his colleague Meyer, constructed an eight-column table of elements, in which components with similar qualities were grouped.
Mendeleev's table, which grouped the elements in increasing order of atomic mass, demonstrated that the elements' attributes repeated themselves in exact order:
According to Mendeleev, the properties of elements are a periodic function of their atomic mass (periodic law).
As you will see below, Mendeleev's periodic table from 1871 is somewhat different from the one we currently use today, but holds key contribution to the modern periodic table.
What was so special about Mendeleev's periodic table? Well, he foresaw the discovery of new elements and provided places in his periodic table to accommodate them. However, in envisioning periodicity as a basic law determining the nature of the elements, he went considerably further than his predecessors.
Based on that revelation, he famously left an empty position in his table for elements that were left undiscovered if the qualities of a particular element didn't fit the general pattern. The Russian scientist would then name these "hypothetical" elements with prefixes such as eka, dvi, and tri. Those are Sanskrit for one, two and three.
Back then Mendeleev assigned those prefixes to eight unknown elements. For instance, eka-aluminium was named so because it was placed below aluminium on Mendeleev's table, this one later got renamed to Gallium.
It's interesting how he chose Sanskrit no? Not Latin, French, German, Russian or English. Sanskrit! That's so random - how come though?
Well, it is believed that Mendeleev, during his studies at St. Petersburg University in Russia, studied Sanskrit. Why would he use an ancient Indian language in his studies though?
The Sanskrit alphabet, which Mendeleev's mentor was well-versed in, was a periodic system itself: the arrangement of the Sanskrit alphabet explained how letters may join to produce sounds in the same way as the periodic table of elements demonstrates how distinct elements can mix to form compounds.
With success comes failures though. Remember the trial and error process I mentioned above? Well, our Russian scientists fell victim to it.
Unfortunately, there were some limitations to Mendeleev's periodic table. In fact, his table was unable to explain some things such as the fact that cobalt, despite having an atomic mass greater than that of nickel, has properties that could place it before this element. These inconsistencies made it difficult to have a proper understanding of the elements.
So as you can see that atomic mass is not a perfect predictor of elemental properties, what is more often used today is the proton number (also known as atomic number). The modern periodic table is up next, and we can see this manifestation there!
As mentioned above, the periodic law was reexamined due to some inconsistencies in the categorization of elements based on atomic mass.
Periodic law today is based on the fact that the properties of elements are a function of their atomic number rather than their mass.
Now that we got the history out of the way, let's go into the nitty and gritty part of the periodic table: its organization and how to understand it!
The periodic table is a list of chemical elements ordered by their atomic number, qualities, and features.
The International Union of Pure and Applied Chemistry (IUPAC) has confirmed 118 elements, amongst which:
The periodic table organizes and localizes all known elements into groups, periods, blocks, metals, nonmetals, nonmetals, lanthanoids, and actinides based on their characteristics and relationships to one another.
Groups are the columns of the periodic table. They indicate chemical elements with similar chemical and physical properties.
Some groups have their own characteristics, let's check them out!
Alkali metals are characterized by high reactivity, low ionization energy, low electronegativity and negative reduction potential. They tend to only form compounds in their +1 oxidation state.
Alkaline Earth Metals are soft and have low density, they are very reactive, although less than those of group 1, and form compounds only in the oxidation state +2.
Halogens are highly reactive elements, that when reacting with metals, form salts. For instance,
if we were to combine 2 Na, a metal with 2 Cl2, a halogen, we get 2 NaCl and a lot of heat. This is called the "salt lamp experiment". Here you lower molten sodium into the chlorine atmosphere and you get a bright orange light and some salt.
Noble gases are characterized by a closed electronic structure, a duet for helium, and an octet for the others. These configurations are particularly stable and explain their zero or poor reactivity. They are monoatomic, colourless, odourless, tasteless and non-flammable.
The periodic table has seven horizontal lines known as periods. They are arranged in the order of their atomic numbers. They are related to the concept of principal quantum number, essentially the number of the row corresponds to the principal quantum of the valance electron orbitals. Confusing here is an example:
If the outermost orbital is called 5s you would get 5 as the principal quantum number and consequently, it will be in the 5th row of elements. Now if your element's outermost orbital is 3d this guy would be placed in the 3rd row, easy right?
The first period is the shortest as it has only two elements (H and He) because the elements have electrons only in an s-type orbital. They represent the first energy level (n = 1).
The second and third periods have eight elements. The electrons here are only in the s and p orbitals. They represent the chemical elements of the second (n = 2) and third (n = 3) energy levels respectively.
The fourth and fifth periods have 18 elements, and the electrons here have d-type orbitals.
Starting from the 6th you can get f orbitals too.
Transition metals, are malleable and ductile, conduct heat and electricity and form positive ions.
Inner-transition metals, as mentioned above, are an extension of group 3. They can be divided into two subcategories:
While lanthanides never exhibit more than two oxidation states and give essentially ionic compounds, actinides exhibit a greater number of oxidation states and the presence of oxidation states stabilizes covalent bonds and facilitates the formation of complexes.
There are three types of elements that make up the periodic table, based on their chemical and physical properties: metals, metalloids and non-metals.
The Periodic Table is a rather complicated beast, and we could go over so much more about it, but I hope this was enough for you to get the most important parts of it. If you still want more keep reading our other articles on the topic!
In 1869 Mendeleev proposed that the properties of the elements were a function of their atomic mass. The Russian scientist, alongside his colleague Meyer, constructed an eight-column table of elements, in which components with similar qualities were grouped.
Mendeleev's table, which grouped the elements in increasing order of atomic mass, demonstrated that the elements' attributes repeated themselves in exact order:
According to Mendeleev, the properties of elements are a periodic function of their atomic mass (periodic law).
The groups of the periodic table are the columns, while the periods are the rows.
The elements are listed in order of their atomic number (number of protons). Each group of the periodic table indicates elements with similar chemical properties, such as electron configuration, reactivity, and electronegativity.
Elements on the periodic table are organized as follows:
In 1869 Mendeleev proposed that the properties of the elements were a function of their atomic mass. The Russian scientist, alongside his colleague Meyer, constructed an eight-column table of elements, in which components with similar qualities were grouped.
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